if you scroll down on that page, you will see that you can program the xl-5 esc, doesn't matter what radio you are using.. it's got three modes:
Sport Mode (Profile #1: 100% Forward, 100% Brakes, 100% Reverse)
Race Mode (Profile #2: 100% Forward, 100% Brakes, No Reverse)
Training Mode (Profile #3: 50% Forward, 100% Brakes, 50% Reverse)
beyond that, you'll have to get a radio that allows you to dampen the throttle, brakes, etc to adjust it further..
I would guess it's only good to about 9v or so... maybe 10v if you really want to push it.. jumping from 2s to 3s is a pretty significant leap.. a fully charged 3s is 12.6v! when I put a 2s back on my MERV you really get a sense of how much more power a 3s is.. anyways.. 2s with a good motor should get the WK moving along nicely! on a 3s you're just going to break stuff.